Journal of Organometallic Chemistry p. 115 - 122 (1981)
Update date:2022-08-05
Topics:
Chaudret, B.
Poilblanc, R.
The reactions between RuH2(PPh3)4 or RuH4(PPh3)3 and 1,2-di(isopropylimino)ethane (DAD-A), 2,3-di(phenylimino)butane DAD-C) and 1,2-di(p-methoxyphenylimino)ethane (DAD-D) in toluene produce symmetrical trans dihydrido complexes.However the product obtained from DAD-C is difficult to isolate, and attempts to prepare it in alkanes led to the isolation of hexa-coordinate cis-dihydrido and pentacoordinate cis-dihydrido complexes in which the diazadiene is coordinated only through one end.A scheme showing the proposed reaction sequence is presented.
Contact:(86) 731 88718666
Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Hangzhou Ocean Chemical Co., Ltd.
website:http://www.hzoceanchem.com
Contact:+86-571-88025872, 28272092, 28272096
Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China
Beijing Mashi Fine Chemical Co.,Ltd.
Contact:+86-10-61271592
Address:Room 506, Section B, Kaichi Mansion, Industrial Development
Chongqing maohuan Chemicals Co., Ltd
website:http://www.bschem.com
Contact:+86 13996103726
Address:Chongqing Nan'an District Tu Town
wuxi leji biology technology co., LTD
website:http://www.lejibio.com/
Contact:18362718864
Address:The Nanyue Road No. 2, Yixing City, Jiangsu Province
Doi:10.1021/jo01231a010
(1936)Doi:10.1007/BF00899326
(1950)Doi:10.1002/ardp.200700143
(2007)Doi:10.1016/j.bmcl.2004.01.104
(2004)Doi:10.1021/jm00139a003
(1981)Doi:10.1016/j.cclet.2013.04.002
(2013)
