Halogenation of Alkyl p-Tolyl Sulfones with Carbon Tetrahalides. Application to the Synthesis of Aromatic Ketones

DOI: 10.1246/bcsj.53.3027

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3027 - 3028 (1980)

Update date:2022-08-04

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Authors:

Kotake, Hiroshi

Inomata, Katsuhiko

Kinoshita, Hideki

Sakamoto, Yasuko

Kaneto, Yoko

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Article abstract of DOI:10.1246/bcsj.53.3027

Carbanions of alkyl p-tolyl sulfones reacted with carbon tetrahalides to give the corresponding polyhalogenated products in good yields.Some chlorinated sulfones were converted to unsymmetrical ketones by treatment with silver perchlorate in trifluoroacetic acid.

Full text of DOI:10.1246/bcsj.53.3027

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