AN INVESTIGATION OF THE ELECTRON TRANSFER PROPERTIES OF MODIFIED ORGANOCOPPER REAGENTS AND HIGHER-ORDER CUPRATES

DOI: 10.1016/0040-4020(89)80079-1

Source and publish data:

Tetrahedron p. 517 - 522 (1989)

Update date:2022-08-03

Topics:

Authors:

Smith, Robin A. J.

Vellekoop, A. Samuel

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Article abstract of DOI:10.1016/0040-4020(89)80079-1

The electron transfer properties of organocopper reagents are attenuated on introduction of BF3OEt2 or Me3SiCl.The results are interpreted in concordance with current mechanistic proposals.Higher-order CuCN-based cuprates show significant electron transfer ability, in contrast to the related lower-order cuprates.

Full text of DOI:10.1016/0040-4020(89)80079-1

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