A GENERAL SYNTHETIC METHOD OF 1,2-DIHYDROCYCLOBUTACOUMARIN AND ITS 1-SUBSTITUTED DERIVATIVES

DOI: 10.1246/cl.1981.423

Source and publish data:

Chemistry Letters p. 423 - 426 (1981)

Update date:2022-08-03

Topics:

Authors:

Naito, Toshihiko

Nakayama, Nayomi

Kaneko, Chikara

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1981.423

4-Methoxycoumarin reacts photochemically with ethylene and its substituted derivatives to form 8b-methoxy-1,2,2a,8b-tetrahydro-cyclobutacoumarin and its 1-substituted derivatives, which in turn eliminate methanol by boron trifluoride etherate in benzene to give the corresponding 1,2-dihydrocyclobutacoumarins in high overall yields.

Full text of DOI:10.1246/cl.1981.423

Products guided by the article

Product name:2-(2-Hydroxy-phenyl)-3,3-dimethyl-cyclobut-1-enecarboxylic acid methyl ester

Cas No:77959-01-4

R&D Labs maybe for 77959-01-4

Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Zhejiang Sucon Silicone Co.,Ltd

Contact:+86-575-88046692

Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Jinan Hongfangde Pharmatech Co.LTD

Contact:0531-88870908

Address:F Bldg,750#,Shunhua Rd,New&High-tech Zone,Jinan,Shandong,China 250101
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China

Relevant to this article

NEW YLIDE ANIONS. A VINYL ANION EQUIVALENT FOR SUBSTITUTED FUMARATE ESTERS

Doi:10.1016/0040-4039(81)80105-0
(1981)
Negative kinetic temperature effect on the hydride transfer from NADH analogue BNAH to the radical cation of N-benzylphenothiazine in acetonitrile

Doi:10.1021/jo061145c
(2006)
β-D-Fructofuranosyl α-D-arabino-hexopyranosid-2-ulose (2-ketosucrose)

Doi:10.1016/S0008-6215(00)80403-6
(1981)
The unexpected synthesis of 2-thioxo-1-imidazolidinecarboxamides from 2-oxo-1-imidazolidinethiocarbonyl chloride

Doi:10.1016/S0040-4039(00)97165-X
(1990)
Doi:10.1021/ja01060a032
(1964)
N,N-Dihalophosphoramides-XII¹ 1 Part XI: A. Zwierzak amd K. Osowska, Angew. Chem. 88, 302 (1976). The addition of diethyl N,N-dichlorophosphoroamidate (dcpa) to α-pinene and norbornene

Doi:10.1016/0040-4020(78)80118-5
(1978)

Article Doi