Journal of the Chemical Society. Perkin transactions I p. 746 - 750 (1981)
Update date:2022-08-03
Topics:
Yasuda, Masahide
Pac, Chyondgjin
Sakurai, Hiroshi
Efficient photocyanation of various arenes with sodium cyanide in 9:1 acetonitrile-water occurs in the presence of such electron acceptors as p-dicyanobenzene, 1-cyanonaphthalene, or 9-cyanophenanthrene.Under nitrogen, photocyanation of phenanthrene, anthracene, naphthalene, and 2,3-dimethylnaphthalene gives both the corresponding hydrocyanation products and the aromatic nitriles, while complex mixtures are formed with other arenes.Under oxygen, a variety of arenes which are electron donors in nature can be efficiently cyanated upon irradiation to give the aromatic nitriles.Cyanation of naphthalene derivatives gives only 1-cyanonaphthalene compounds whereas phenanthrene and anthracene are cyanated at C-9.
View MoreXi'an North Information Industry Co., Ltd. Weilv Chemical Department
Contact:+86-29-88156413
Address:Jixiang Road 99 Xi'an Shaanxi Province
Changsha Huajing Powdery Material Technological Co., Ltd.
Contact:86-731-88879686
Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Skyrun Industrial Co.,Ltd(expird)
website:http://www.chinaskyrun.com
Contact:0086-576-84610586
Address:Chemical Development Zone
Contact:21-7631221 15884421033
Address:326 Science and technology,Shanghai,China
Buffett (China) Holding Co.,Ltd
Contact:4006570891
Address:
Doi:10.1021/jm030548r
(2004)Doi:10.1039/DT9810000793
(1981)Doi:10.1016/S0022-328X(00)81479-5
(1981)Doi:10.1002/anie.201703109
(2017)Doi:10.1016/j.bmc.2004.07.066
(2004)Doi:10.1016/j.tetlet.2004.08.031
(2004)
