Asymmetric synthesis of α-methyl carboxylic acid derivatives stereochemistry in acidic ring opening of epoxides

DOI: 10.1016/S0040-4039(00)74487-X

Source and publish data:

Tetrahedron Letters p. 1059 - 1062 (1991)

Update date:2022-09-26

Topics:

Authors:

Fukumasa

Furuhashi

Umezawa Umezawa

Takahashi

Hirai Hirai

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Article abstract of DOI:10.1016/S0040-4039(00)74487-X

Optically active α-methyl carboxylic acid derivatives were prepared via reaction of microbially produced epoxides with trimethylaluminum. Stereochemistry of the ring opening reaction was discussed through an MO calculation.

Full text of DOI:10.1016/S0040-4039(00)74487-X

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