Journal of Organic Chemistry p. 3764 - 3767 (1981)
Update date:2022-08-04
Topics: Stereoselective Functionalized Carbohydrates Geminal Alkyl Derivatives
Fraser-Reid, Bert
Tsang, Raymond
Tulshian, Deen Bundhu
Sun, King Mo
2-, 3-, and 4-Keto derivatives of some α-D-hexopyranosides react with Ph3P=CHCOOEt to give a single geometric isomer in each case, which is readily converted into an allyl vinyl ether.Claisen rearrangements of the latter proceed with high stereoselectivit
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