
Journal of the Chemical Society. Chemical communications p. 241 - 242 (1981)
Update date:2022-08-05
Topics:
Meth-Cohn, Otto
Rhouati, Salah
Phenyl azidoformates give benzoxazolones on 'spray pyrolysis' by direct nitrene attack at the ortho-position and α-naphthyl azidoformate gives a naphthoxazolone only by β-attack; biphenyl-2-yl azidoformate gives both 7-phenylbenzoxazolone and an azepine by nitrene attack of the adjacent ring while 2,6-dimethylphenyl azidoformate gives the endo-Diels-Alder dimer of 6-isocyanato-2,6-dimethylcyclohexa-2,4-dienone under the same conditions.
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(1981)Doi:10.1002/ardp.19813140614
(1981)Doi:10.1248/cpb.50.649
(2002)Doi:10.1002/jhet.5570200437
(1983)Doi:10.1007/BF00949735
(1981)