Journal of the Chemical Society. Perkin transactions II p. 393 - 398 (1981)
Update date:2022-08-03
Topics:
Deniau, Jean
Duong, Kiem N. V.
Gaudemer, Alain
Bougeard, Peter
Johnson, Michael D.
Alkyl- and benzyl-bis(dimethylglyoximato)pyridinecobalt(III) complexes react with diphenyl disulphide or diphenyl diselenide, thermally and photochemically, to give good yields of alkyl or benzyl phenyl sulphides or selenides.Chiral alkylcobalt(III) complexes react to give racemic alkyl phenyl sulphides or selenides.Allyl- and propadienyl-bis(dimethylglyoxymato)pyridinecobalt(III) complexes react similarly to give the thermodynamically more stable allyl, propadienyl, or propynyl phenyl sulphides or selenides.These reactions are interpreted in terms of free radical processes in which organic radicals formed as a result of thermal, photochemical, or chemically induced homolysis of the organocobalt complex, attack the diphenyl dichalcogenide to give the product organo phenyl chalcogenide.No evidence could be obtained for the direct attack of phenylthiyl or phenylselenyl radicals on the organic ligand of the organocobalt complexes, though this process cannot be excluded in the case of allylcobalt complexes.
Contact:86-28-61993785
Address:No.70-13-21, North Section, Erhuan
Suzhou HeChuang Chemical Co.,Ltd.
Contact:+86-512-88800520
Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Hangzhou Taiyan Trading Co., Ltd(expird)
Contact:+86-13777583958
Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Shanghai Forever Synthesis Co.,Ltd.
Contact:021-61124658
Address:Zhoukang Road,Pudong New District,Shanghai,China
NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD
Contact:86-0951-7815345
Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China
Doi:10.1055/s-0033-1338744
(2013)Doi:10.1016/S0040-4039(01)90465-4
(1981)Doi:10.1039/c39810000364
(1981)Doi:10.1016/S0040-4039(01)90354-5
(1981)Doi:10.1021/jo00335a066
(1981)Doi:10.1021/acs.orglett.6b03394
(2016)
