NEW SYNTHETIC METHOD FOR ORSELLIC ACID TYPE MACROLIDES BY INTRAMOLECULAR ALKYLATION OF PROTECTED CYANOHYDRIN. THE SYNTHESIS OF (+/-)-ZEARALENON.

DOI: 10.1016/S0040-4039(01)90320-X

Source and publish data:

Tetrahedron Letters p. 1363 - 1366 (1981)

Update date:2022-08-04

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Authors:

Takahashi, Takashi

Ikeda, Hiroshi

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(01)90320-X

Zearalenone was synthesized by a general cyclization method of orsellic acid type macrolides having ketone moiety using the intramolecular alkylation of the protected cyanohydrin.This alkylation tolerates the presence of ester group and requires short rea

Full text of DOI:10.1016/S0040-4039(01)90320-X

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