Journal of the American Chemical Society p. 5414 - 5417 (1981)
Update date:2022-08-03
Topics:
Cameron, Tim B.
El-Kabbani, Fiesal M.
Pinnick, Harold W.
Flash vacuum thermolysis of 1,3-dioxolane-4-ones yields aldehydes and ketones as the major products as the result of apparent decarboxylation of α lactones formed by collapse of a 1,3 dipole.When phenyl substituents are present, epoxides are also formed via the intermediacy of a carbonyl ylide.
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