Oxytallation Adduct Intermediate in Hydration of Terminal Acetylenes by Thallium(III) Salt Catalyst

DOI: 10.1039/P19810000991

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 991 - 994 (1981)

Update date:2022-08-04

Topics:

Authors:

Uemura, Sakae

Miyoshi, Haruo

Okano, Masaya

Ichikawa, Katsuhiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19810000991

Reaction of several terminal acetylenes with thallium(III) acetate in chloroform or acetic acid gives a white solid in good yield which is believed to be a new type of oxythallation adduct, (2), on the evidence available to date.From the fact that it is converted into the corresponding ketone and inorganic thallium(III) salt by heating in acetic acid or methanol, it is concluded that it is one of the intermediates in the thallium(III) salt-catalysed conversion of terminal acetylenes into ketones.

Full text of DOI:10.1039/P19810000991

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(C₆H₅(O₂CCH₃)C₂Tl(O₂CCH₃))2

Cas No:78793-82-5

R&D Labs maybe for 78793-82-5

Hangzhou innopharma technology Co,.Ltd.(expird)

Contact:+86-13388601988

Address:Room845,lixin building, moganshan road, hangzhou, china
Taixing Shenfeng Chemical Co., Ltd.

Contact:+86-523-87117033, 87117666

Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.
jiangsu senxuan pharmaceutical and chemical co.,ltd

Contact:86-523-87982810

Address:hongqiao industrial zone,taixing,jiangsu china
Wuhan Silworld Chemical Co.,Ltd

website:http://www.silworldchemical.com

Contact:+86-27-85613400

Address:No.198 jiangjun Road, Wuhan,China 430033
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province

Relevant to this article

Syntheses in the Isocamphane Series, XV. The Isocamphaneanalogous Mandelic Acid

Doi:10.1007/BF00901831
(1981)
Synthesis of 2-Phenyl-4H-thiopyran-4-one

Doi:10.1021/jo00335a070
(1981)
A ring-rearrangement metathesis approach toward the synthesis of cyclopenta- and cyclohexa[c]indene systems

Doi:10.1021/ol048650l
(2004)
Ortho Vinylation of Aromatic Amides via Cyclopalladation Complexes

Doi:10.1021/jo00335a019
(1981)
Doi:10.1007/BF00778855
()
Total synthesis of catenioblin B

Doi:10.1016/j.tetlet.2014.09.034
(2014)

Article Doi