Tetrahedron Letters p. 5677 - 5680 (1987)
Update date:2022-08-02
Topics:
Sato, Toshio
Itoh, Takatoshi
Fujisawa, Tamotsu
α-Alkylation of the dianions of β-hydroxy sulfoxides proceeds with high 1,2-asymmetric induction to give threo-α-alkyl-β-hydroxy sulfoxides.The utility of the present reaction was demonstrated in the asymmetric synthesis of (+)- and (-)-cis-7,8-epoxy-2-methyloctadecanes (disparlure).
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