Tetrahedron Letters p. 4073 - 4076 (1981)
Update date:2022-07-29
Topics: Ester Alcohols Dehydrogenation Catalysis Primary alcohols Preliminary Liquid Phase Copper oxide Observations
Berthon, Bruno
Forestiere, Alain
Leleu, Gerard
Sillion, Bernard
Linear primary alcohols with at least 7 carbon atoms are quite quantitatively transformed in esters, by CuO, at temperatures > 17O deg C, without air in liquid phase. Preponderant influence of carbon in position 2 is evidenced.In the same conditions lactones are obtained from diols, and benzylic alcohols undergoes, by hydride transfer, a disproportionation into toluene, benzaldehyde and water.
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Doi:10.1021/ja00531a054
(1980)Doi:10.1016/S0040-4020(01)92350-6
(1981)Doi:10.1021/jo00403a006
(1978)Doi:10.1016/S0040-4039(01)86312-7
(1979)Doi:10.1016/j.tet.2011.09.056
(2011)Doi:10.1002/jlac.198119811222
(1981)
