An Example of Substitution proceeding with Retention in the SRN1 Reaction. Trapping of a Pyramidal Benzylic Radical by Benzenethiolate Ion

DOI: 10.1039/c39810000079

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Journal of the Chemical Society. Chemical communications p. 79 - 80 (1981)

Update date:2022-08-03

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Authors:

Norris, Robert K.

Smyth-King, Rosalind J

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Article abstract of DOI:10.1039/c39810000079

The S_RN1 reaction of c-4-t-butyl-c-2-methyl-r-1-nitro-1-p-nitrophenylcyclohexane with sodium benzenethiolate in hexamethylphosphoramide, which proceeds with retention of configuration at C-1 at relatively high thiolate concentrations, and with

Full text of DOI:10.1039/c39810000079

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