Reaction of Carbohydrate Halides with Magnesium. Novel C-C Coupling of Sugar Derivatives via Organometallic Intermediates

DOI: 10.1021/jo00338a029

Source and publish data:

Journal of Organic Chemistry p. 5204 - 5212 (1981)

Update date:2022-08-05

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Authors:

Ariatti, Mario

Zemlicka, Jiri

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Article abstract of DOI:10.1021/jo00338a029

The reaction of 3-deoxy-3-C-(iodomethyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose (1c) with sublimed magnesium in refluxing tetrahydrofuran gave dimer 2 and only traces of the 3-deoxy-3-methyl derivative 1d.Similarly methyl 5-deoxy-5-iodo-2,3-O-isopro

Full text of DOI:10.1021/jo00338a029

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