Functionalization of Alkenes and Alkynes with benzene. Bis(tosyloxy)alkanes, Vinylaryliodonium Tosylates, and Alkynylaryliodonium Tosylates

DOI: 10.1021/jo00334a057

Source and publish data:

Journal of Organic Chemistry p. 4324 - 4326 (1981)

Update date:2022-08-05

Topics:

Authors:

Koser, Gerald F.

Rebrovic, Louis

Wettach, Richard H.

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Article abstract of DOI:10.1021/jo00334a057

benzene (1) reacts with various alkenes to give bis(tosyloxy)alkanes and with various alkynes to give either vinylaryliodoniumtosylates or alkynylaryliodonium tosylates.In the presence of 1, 1,1-diphenylethylene undergoes oxidative rearrangement and phenyliodination.

Full text of DOI:10.1021/jo00334a057

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