Inorganic Chemistry p. 146 - 156 (1982)
Update date:2022-08-05
Topics:
Collman, James P.
Rothrock, Richard K.
Finke, Richard G.
Moore, Eric J.
Rose-Munch, Fran?oise
The synthesis, characterization, and ligand substitution reactions of Fe2(PPh2)2(CO)6 (1) and Na2Fe2(PPh2)2(CO) 6·5THF (4) are presented. Reaction of 4 with alkylating agents affords directly the acyl complexes NaFe2(PPh2)2(CO)5[C(O)R]·THF, (6). A mechanism involving intramolecular, metal-promoted alkyl migration is proposed. Reaction of 1 with lithium reagents affords LiFe2(PPh2)2(CO) 5[C(O)R]·3THF.
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Doi:10.1021/jo00337a030
(1981)Doi:10.1055/s-1981-29509
(1981)Doi:10.1134/S0020168509050197
(2009)Doi:10.1016/j.crci.2014.01.003
(2014)Doi:10.1021/ic00131a060
(1982)Doi:10.1016/S0040-4039(01)81816-5
(1981)
