Tetrahedron Letters p. 2575 - 2578 (1981)
Update date:2022-08-05
Topics:
Tsuji, Jiro
Kataoka, Hideaki
Kobayashi, Yuichi
1,3-Diene monoepoxides react with nucleophiles in the presence of palladium complex as a catalyst under neutral conditions to give 1,4-adducts selectively.The 1,4-adducts are allylic alcohols and there is a possibility of another nucleophilic attack.Ester of Monarch butterfly pheromone was prepared.
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