Reaction of Alkoxides with (Phenylthio)carbene: A Novel Oxyanionic Substituent Effect on the C-H Insertion of Carbenes

DOI: 10.1021/ja00409a079

Source and publish data:

Journal of the American Chemical Society p. 5965 - 5967 (1981)

Update date:2022-07-30

Topics: Regioselectivity   Nucleophile   Electrophile   Deprotonation   Carbene   Steric Effects   Reaction Mechanism   Electronic effects   Kinetic Study   Synthetic Utility   Spectroscopic Analysis   Thermodynamic Control   C-H Insertion   Insertion reaction   reactive intermediate   Substituent effect   ALKOXIDES   Anionic Intermediate  

Authors:

Harada, Toshiro

Oku, Akira