Journal of the Chemical Society. Perkin transactions I p. 2091 - 2095 (1981)
Update date:2022-08-04
Topics:
Giles, Robin G. F.
Mitchell, Peter R. K.
Roos, Gregory H. P.
Struempfer, Jacobus M. M.
Syntheses of diastereoisomeric 5-hydroxy-2-(4'-hydroxy-γ-butyrolacton-5'-yl)-1,4-naphthoquinones (1) and (2) and their 5-deoxy-analogues (3) and (4) are described.The stereochemistries of the latter, being defined through unambiguous synthesis, permit the assignment of the configurations of (1) and (2) (which were obtained from a single precursor) and also those of the natural products, juglomycins A and B.
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Doi:10.1016/0040-4020(77)80303-7
(1977)Doi:10.1021/ja01143a042
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(1981)Doi:10.1002/hlca.19810640532
(1981)
