CHEMIE POLYFUNKTIONELLER LIGANDEN LXIII. ADAMANTANKAEFIGVERBINDUNGEN MIT DEN HETEROELEMENTEN ARSEN, STICKSTOFF UND SILIZIUM

Article abstract of DOI:10.1016/S0022-328X(00)80127-8

The reaction of 1,1,1-tris(diiodarsinomethyl)ethane, CH3C(CH2AsI2)3 (I), with i-C3H7NH2, n-C4H9NH2, C6H5NH2, p-CH3C6H4NH2 and <(CH3)3Si>2NH in the presence of (C2H5)3N as auxiliary base in THF gives the adamantane cage compounds CH3C(CH2AsNC3H7)3 (III), C