A Total Synthesis of Racemic Senepoxide: Formal Syntheses of Crotepoxide and Pipoxide

DOI: 10.1021/jo00338a051

Source and publish data:

Journal of Organic Chemistry p. 5252 - 5253 (1981)

Update date:2022-08-04

Topics:

Authors:

Schlessinger, R. H.

Lopes, A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00338a051

Diels-Alder reaction of 1-(triethylsiloxy)-buta-1,3-diene with ethyl propiolate affords an exellent yield of the dihydrobenzene adduct 2 which has been transformed into senepoxide.Formal syntheses of crotepoxide andd pipoxide also have been carried out from 2.

Full text of DOI:10.1021/jo00338a051

Products guided by the article

Product name:6-Triethylsilanyloxy-cyclohexa-1,4-dienecarboxylic acid ethyl ester

Cas No:79746-16-0

R&D Labs maybe for 79746-16-0

Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
Nanjing lanbai chemical Co.,Ltd.

Contact:+86-25-85499326

Address:Room 908, 9F Taiyue Building,No.285 Heyan Road
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

website:http://www.bjgreenchem.com/

Contact:+86-427-6515887

Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
Shandong Xingshun New Material Co., Ltd.

website:http://www.sd-xingshun.com

Contact:+86-519-86461196

Address:Middle of Luhua East Road, Dingtao District
Zhejiang Chemline International Co., Ltd.

Contact:+86-571-88062298

Address:Hengdian Industry Area, Dongyang, Zhejiang, China

Relevant to this article

Nuclear Magnetic Resonance Studies of Terpenes with Chiral and Achiral Lanthanide(III)-Silver(I) Binuclear Shift Reagents

Doi:10.1021/ja00366a003
(1982)
Synthesis and characterization of salts of the bis(diisopropylamido)boron(III) cation and attempted reactions to make the corresponding bis(dimethylamido)boron(III) cation

Doi:10.1021/ic00132a049
(1982)
EIGHT CAROTANE SESQUITERPENES FROM FERULA LINKII

Doi:10.1016/S0031-9422(00)84095-9
(1984)
C-Nucleoside Studies. Part 13. A New Synthesis of 2,3,5-Tri-O-benzyl-α(and β)-D-ribofuranosylethyne Involving Benzyloxy Participation, and a Synthesis of α-Showdomycin

Doi:10.1039/P19810002267
(1981)
Enantioselective synthesis of (1S,2S)-1,2-di-tert-butyl and (1R,2R)-1,2-di-(1-adamantyl)ethylenediamines

Doi:10.1016/j.tetlet.2004.08.164
(2004)
Molecular modeling, synthesis, and preliminary biological evaluation of glutathione-S-transferase inhibitors as potential therapeutic agents

Doi:10.1021/jm0504609
(2005)

Article Doi