A Total Synthesis of Racemic Senepoxide: Formal Syntheses of Crotepoxide and Pipoxide

DOI: 10.1021/jo00338a051

Source and publish data:

Journal of Organic Chemistry p. 5252 - 5253 (1981)

Update date:2022-08-04

Topics:

Authors:

Schlessinger, R. H.

Lopes, A.

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Article abstract of DOI:10.1021/jo00338a051

Diels-Alder reaction of 1-(triethylsiloxy)-buta-1,3-diene with ethyl propiolate affords an exellent yield of the dihydrobenzene adduct 2 which has been transformed into senepoxide.Formal syntheses of crotepoxide andd pipoxide also have been carried out from 2.

Full text of DOI:10.1021/jo00338a051

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