Journal of Organic Chemistry p. 287 - 292 (1982)
Update date:2022-08-06
Topics:
Andrews, Ursula Holle
Baldwin, John E.
Grayston, Michael W.
The thermal isomerization of trans-1,2-dideuteriocyclooctene in adequately conditioned Pyrex ampules gives cis-1,2-dideuteriocyclooctene, a result which excludes radical chain, <1,3> hydrogen shift, and <1,2> hydrogen shift mechanisms.When inadequately conditioned ampules are employed, deuterium scrambling is evident in the cis-cyclooctene formed but not in the trans-cyclooctene recovered.
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