Journal of the Chemical Society. Perkin transactions I p. 1969 - 1980 (1981)
Update date:2022-08-05
Topics:
Mageswaran, Sivapathasuntharam
Ollis, W. David
Southam, Dolores A.
Sutherland, Ian O.
Thebtaranonth, Yodhathai
The propynylammonium salt (5) reacts with aqueous sodium hydroxide to give the allene (7) and a new ylide (11).The simultaneous formation of (7) and (11) suggests that the apparent <3,2> sigmatropic rearrangement of the propynyl ylide (6) to the allene (7
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