
Journal of Organometallic Chemistry p. 315 - 320 (1981)
Update date:2022-07-31
Topics:
Gielen, Marcel
Eynde, Ivan Vanden
The cleavages of the trityl-tin bond by NaFe(CO)2Cp, LiBHEt3 and Ph3SnLi are not stereoselective.This is explained in terms of a one-electron transfer mechanism leading to a triorganostannyl radical which can undergo inversion before reacting with another radical to give the product.
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