BORON TRIFLUORIDE-CATALYZED OXIDATION OF GLYCAL ESTERS: AN EFFECTIVE AND MILD METHOD FOR THEIR CONVERSION INTO α,β-UNSATURATED LACTONES

DOI: 10.1016/S0040-4039(00)87705-9

Source and publish data:

Tetrahedron Letters p. 3781 - 3784 (1982)

Update date:2022-08-04

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Authors:

Jarglis, Pan

Lichtenthaler, Frieder W.

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Article abstract of DOI:10.1016/S0040-4039(00)87705-9

An effective, one-step procedure for conversion of glycal and 2-acyloxyglycal esters to 2,3-unsaturated lactones has been developed, involving BF3-induced removal of the allylic acyloxy function and oxidation with m-chloroperbenzoic acid or pyridinium chl

Full text of DOI:10.1016/S0040-4039(00)87705-9

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