A SIMPLE NEW GENERAL SYNTHESIS OF MACROCYCLIC KETONES: A NEW ENTRY TO THE SYNTHESIS OF EXALTONE AND (+/-)-MUSCONE

DOI: 10.1016/S0040-4039(00)96432-3

Source and publish data:

Tetrahedron Letters p. 3963 - 3966 (1987)

Update date:2022-07-30

Topics:

Authors:

Suginome, Hiroshi

Yamada, Shinji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96432-3

We describe an efficient new synthesis of 15-membered cyclic ketones, exaltone and (+/-)-muscone, based on a three-carbon annelation of cyclic ketones followed by the regioselective radical cleavage of the fused bond of the resulting bicyclic systems.

Full text of DOI:10.1016/S0040-4039(00)96432-3

Products guided by the article

Product name:2-(3-p-toluene-sulfonyloxy-prop-1-yl)-cyclododecanone

Cas No:80007-44-9

R&D Labs maybe for 80007-44-9

Sanming Coffer Fine Chemical Industrial Co., Ltd

website:http://www.cofferxm.com/

Contact:+86-598-5853979

Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China
Hubei ShiNan Pharmaceutical Chemical co., Ltd.(expird)

Contact:+86-13554447107

Address:Wuhan HongShanOu wu no road 378 future residence building 1 unit 14 layer no. 1401 A
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
hangzhou verychem science and technology co.ltd

website:http://www.verypharm.com

Contact:+86-571-88162785; 88162786

Address:F1502, 753 Shenhua road, Hangzhou, China
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002

Relevant to this article

Synthesis of phosphorus(V)-stabilized geminal dianions. the cases of mixed P=X/PBH₃ (X = S, O) and P=S/SiMe₃ derivatives

Doi:10.1021/om300954a
(2013)
Development of an acyl sulfonamide anti-proliferative agent, ly573636 ? na

Doi:10.1021/op800210x
(2009)
Supramolecular Organization of Dye Molecules in Zeolite L Channels: Synthesis, Properties, and Composite Materials

Doi:10.1002/chem.201504404
(2016)
Pd(OH)₂/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to α,β-enones or β-Silyloxy-α,β-enones

Doi:10.1021/ol050284y
(2005)
A new synthetic route to indoloquinones: Formal synthesis of ellipticine

Doi:10.1055/s-2005-864826
(2005)
Synthesis and in vitro antimicrobial activity of 6-substituted 2H-1,3,5-thiadiazine-2,4(3H)-diones

Doi:10.1021/jm00346a028
(1982)

Article Doi