A SIMPLE NEW GENERAL SYNTHESIS OF MACROCYCLIC KETONES: A NEW ENTRY TO THE SYNTHESIS OF EXALTONE AND (+/-)-MUSCONE

DOI: 10.1016/S0040-4039(00)96432-3

Source and publish data:

Tetrahedron Letters p. 3963 - 3966 (1987)

Update date:2022-07-30

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Authors:

Suginome, Hiroshi

Yamada, Shinji

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Article abstract of DOI:10.1016/S0040-4039(00)96432-3

We describe an efficient new synthesis of 15-membered cyclic ketones, exaltone and (+/-)-muscone, based on a three-carbon annelation of cyclic ketones followed by the regioselective radical cleavage of the fused bond of the resulting bicyclic systems.

Full text of DOI:10.1016/S0040-4039(00)96432-3

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