Tetrahedron Letters p. 3963 - 3966 (1987)
Update date:2022-07-30
Topics:
Suginome, Hiroshi
Yamada, Shinji
We describe an efficient new synthesis of 15-membered cyclic ketones, exaltone and (+/-)-muscone, based on a three-carbon annelation of cyclic ketones followed by the regioselective radical cleavage of the fused bond of the resulting bicyclic systems.
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