Mechanism of the Reaction between Alkyl or Aryl Grignard Reagents and Hexachlorocyclotruphosphazene: An Explanation of Bi(cyclophosphazene) Formation

DOI: 10.1021/ja00347a048

Source and publish data:

Journal of the American Chemical Society p. 2814 - 2819 (1983)

Update date:2022-08-03

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Authors:

Allcock, Harry R.

Desorcie, James L.

Harris, Paul J.

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Article abstract of DOI:10.1021/ja00347a048

An understanding has been obtained of the complex mechanisms that are followed when alkyl or aryl Grignard reagents react with (NPCl2)3 (2) in tetrahydrofuran.The main products are monoalkylcyclotriphosphazenes (3) and bi(cyclotriphosphazenes) (4).The pre

Full text of DOI:10.1021/ja00347a048

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