ON THE STEREOCHEMISTRY OF THE SOLVOLYTIC C/D RING CLEAVAGE OF THE 1,2,3,4,6,7,12,12b-OCTAHYDROINDOLOQUINOLIZINE SYSTEM

DOI: 10.1016/S0040-4020(01)92094-0

Source and publish data:

Tetrahedron p. 1547 - 1556 (1981)

Update date:2022-07-29

Topics:

Authors:

Calverly, M. J.

Harley-Mason, J.

Quarrie, S. A.

Edwards, P. D.

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Article abstract of DOI:10.1016/S0040-4020(01)92094-0

A model sequence for the synthesis of C-mavacurine-type alkaloids is elaborated to demonstrate that substitution at C-12b in the reactions of the amines (4) with cyanogen bromide and methanol (Scheme 6) proceeds with stereospecific inversion of configurat

Full text of DOI:10.1016/S0040-4020(01)92094-0

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