Tetrahedron p. 2451 - 2458 (1981)
Update date:2022-08-03
Topics:
Lamazouere, A. M.
Sotiropoulos, J.
A synthesis of tetrahydropyrimidine-dithiones and octahydroquinazoline-dithiones has been realized by direct action, in basic media, of alkyl or aryl isothiocyanates on ketones possessing at least an hydrogen atom in an α-position.The clarification of the complex mechanism of this reaction has been attempted.It is possible to reach corresponding diones by desulphurization of the dithiones.
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