REACTIVITE DE CARBANIONS &β CETOPHOSPHOROTHIOLATE REARRANGEMENT PHOSPHOROTHIOLATE-PHOSPHATE D'ENOL

DOI: 10.1016/S0040-4020(01)98923-9

Source and publish data:

Tetrahedron p. 3067 - 3070 (1981)

Update date:2022-08-02

Topics:

Authors:

Sturtz, G.

Baboulene, M.

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Article abstract of DOI:10.1016/S0040-4020(01)98923-9

The stabilization of S-alkanoate O,O-dialkyl phosphates carbanions has been tried.An enol phosphate-phosphorothiolate rearrangement is observed and the mechanism is described.This new transposition has been applied to the synthesis of various enol phosphates with thioether of enol function of phytosanitaire interest.

Full text of DOI:10.1016/S0040-4020(01)98923-9

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