REACTIVITE DE CARBANIONS &β CETOPHOSPHOROTHIOLATE REARRANGEMENT PHOSPHOROTHIOLATE-PHOSPHATE D'ENOL

DOI: 10.1016/S0040-4020(01)98923-9

Source and publish data:

Tetrahedron p. 3067 - 3070 (1981)

Update date:2022-08-02

Topics:

Authors:

Sturtz, G.

Baboulene, M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)98923-9

The stabilization of S-alkanoate O,O-dialkyl phosphates carbanions has been tried.An enol phosphate-phosphorothiolate rearrangement is observed and the mechanism is described.This new transposition has been applied to the synthesis of various enol phosphates with thioether of enol function of phytosanitaire interest.

Full text of DOI:10.1016/S0040-4020(01)98923-9

Products guided by the article

Product name:Phosphoric acid (E)-2-(diethoxy-thiophosphorylsulfanyl)-1-phenyl-vinyl ester diethyl ester

Cas No:80410-67-9

R&D Labs maybe for 80410-67-9

SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai
Chemsky（shanghai）International Co.,Ltd.

Contact:0

Address:0
SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
Guangzhou Puho Pharmaceutical Technology Co. Ltd.

Contact:86-20-29848035/29848075

Address:No.166, Chaoyang East Road, Panyu District, Guangzhou City, Guangdong Province
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.

Relevant to this article

Novel and highly selective conversion of alcohols and thiols to alkyl nitrites with triphenylphosphine/2,3-dichloro-5,6-dicyanobenzoquinone/Bu ₄NNO₂ system

Doi:10.1055/s-2004-829122
(2004)
Routes to 3-Aryl-5-phenyl-2-thioacylmethylene-2H-1,3,4-thiadiazolenes

Doi:10.1039/P19810002952
(1981)
REACTION OF PHENYL AZIDE WITH N,N-DIMETHYL-AMINOMETHYLENEPHENYLPHOSPHINES

Doi:10.1007/BF00962146
(1989)
Doi:10.1021/ja01252a039
(1943)
(S)-form of α-methyl-N(α)-phthalimidoglutarimide, but not its (R)-form, enhanced phorbol ester-induced tumor necrosis factor-α production by human leukemia cell HL-60: implication of optical resolution of thalidomidal effects

Doi:10.1248/cpb.42.1157
(1994)
Efficient Large-Scale Radical Deoxygenation in Alcoholic Solvents Using Sodium Hypophosphite and a Phase-Transfer Agent: Application to Erythromycins

Doi:10.1021/jo991645o
(2000)

Article Doi