Tetrahedron p. 3067 - 3070 (1981)
Update date:2022-08-02
Topics:
Sturtz, G.
Baboulene, M.
The stabilization of S-alkanoate O,O-dialkyl phosphates carbanions has been tried.An enol phosphate-phosphorothiolate rearrangement is observed and the mechanism is described.This new transposition has been applied to the synthesis of various enol phosphates with thioether of enol function of phytosanitaire interest.
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