1,3-Dipolar cycloadditions to coordinated azide in cobalt chelate complexes of the type LCo(chelate)N3

DOI: 10.1021/ic00133a069

Source and publish data:

Inorganic Chemistry p. 1226 - 1232 (1982)

Update date:2022-08-02

Topics:

Authors:

Kemmerich, Timm

Nelson, John H.

Takach, Nicholas E.

Boehme, Heiko

Jablonski, Bernd

Beck, Wolfgang

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Article abstract of DOI:10.1021/ic00133a069

Several electron-poor dipolarophiles (alkynes, alkenes, and nitriles) react with azido cobalt chelate complexes of the type LCo(chelate)N₃ under mild conditions. Coordinated five-membered-ring heterocycles are the initial products of these 1,3-

Full text of DOI:10.1021/ic00133a069

Products guided by the article

Product name:(C₆H₅)4As⁽¹⁺⁾*(Co(HONC(CH₃)C(CH₃)NO)2((N₃C₂)(CO₂CH₃)2)2)^(1-)=((C₆H₅)4As)(Co(HONC(CH₃)C(CH₃)NO)2((N₃C₂)(CO₂CH₃)2)2)

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