Reaction de RFI (RF=CnF2n+1, n=4,6,8) en presence de zinc avec les acetates de vinyle et d'allyle: application a la synthese de diols a chaines fluorees

Article abstract of DOI:10.1016/S0022-1139(00)80090-1

The effect of various solvents on the addition of R_FI to vinyl and allyl acetates in the presence of zinc has been studied.The orientation of the reaction towards a dimerisation process has allowed the synthesis of the 1,4-bis(perfluoroalkyl)butane-2,3-diols and 2,3-bis(perfluoroalkyl methyl)butane-1,4-diols in quite good yield.