Enhancement of Rates of Reaction using Neutral Water/Organic Microemulsions as Solvent Media

DOI: 10.1039/c39830000659

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 659 - 660 (1983)

Update date:2022-08-04

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Authors:

Blandamer, Michael J.

Burgess, John

Clark, Barbara

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Article abstract of DOI:10.1039/c39830000659

Relative to the rate constants for reactions in aqueous solutions the rate constants for reactions involving (i) Fe(phen)₃²⁺ (phen = 1,10-phenanthroline), (ii) Fe(5-NO2phen)₃²⁺, (iii) 2,4-dinitrochlorobenzene, and (iv) crystal violet with either hydroxide or cyanide ions are increased markedly when two water/organic microemulsions formed from liquid components are used as reaction media; a similar though less significant change is observed in the related rates of aquation (hydrolysis).

Full text of DOI:10.1039/c39830000659

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