Inorganic Chemistry p. 2276 - 2282 (1982)
Update date:2022-08-03
Topics:
Crutchley
Lever
The photoanation of the bipyrazyl complex Ru(bpz)3(PF6)2, in acetonitrile containing chloride ion, leads to the formation of cis-Ru(bpz)2(CH3CN)Cl+ (maximum quantum yield 0.37), cis-Ru(bpz)2Cl2 (maximum quantum yield 0.001), and an unidentified mono(bipyrazyl)ruthenium(II) derivative. The mechanism of this reaction is discussed. Reaction of M(CO)6 (M = W, Mo) with bipyrazyl yields M(CO)4bpz. The electronic, vibrational, and 1H NMR spectra and electrochemistry of these products were compared with those of their bipyridyl analogues. It is concluded that bipyrazyl is no better a π acceptor than bipyridyl because of weaker σ bonding leaving the metal ion more positvely charged.
Contact:+86-21-61318535
Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
Jiangsu Feymer Technology Co., Ltd.
Contact:+86-512-58110132
Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China
Contact:86-21-50966856
Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Contact:86-791-86629460
Address:1-6F, 118 Xinzhou road, Nanchang, Jiangxi, China
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.
Contact:+86-21-39971718
Address:859 jiadingchengliu shanghai
Doi:10.1021/jo00348a018
(1982)Doi:10.1016/0039-128X(81)90084-2
(1981)Doi:10.1007/BF00513300
(1982)Doi:10.1016/j.bmc.2014.12.005
(2015)Doi:10.1021/jo00134a029
(1982)Doi:10.1039/c39810001218
(1981)
