Journal of the Chemical Society. Perkin transactions I p. 3034 - 3040 (1981)
Update date:2022-09-26
Topics:
Maslinska-Solich, Jolanta
Rudnicka, Irena
Jedlinski, Zbigniew J.
The reaction of chiral aluminium alkoxides (2) <(-)-menthyloxide (2a); (-)-2-methylbutoxide (2b); (-)-2-butoxide (2c); and (-)-2-bornanyl oxide (2d)> with (RS)-2-phenylpropanal (1) gives the optically active (S)-(-)-2-phenylpropyl (R)-(-)-2-phenylpropanoate (3), and the mixed esters (-)-menthyl 2-phenylpropanoate (5a), (+)-2-phenylpropyl 2-methylbutanoate (4b), and (+)-2-methylbutyl 2-phenylpropanoate (5b), respectively.An asymmetric disproportionation reaction mechanism has been proposed for compound (1).
View MoreContact:+86-571-86025531 / 86024803
Address:1218-24 Guangyin Mansion,42 Fengqi East Road
zhengzhou Triz Pharma-Tech Co., Ltd
website:http://www.Trizpharma-tech.com
Contact:+86-0371-86597269，53392065
Address:High-tech Industrial Development Zone, Zhengzhou City, NO.7 Holly Street
Shanghai Synmedia Chemical Co., Ltd
Contact:+86-21-38681880
Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd
Contact:+86-311-80817929
Address:Shangzhuang,Shijiazhuang,China
Shanghai Maxchemco Chemical Industry Co., Ltd.
Contact:(86)21-51079223
Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai
Doi:10.1021/tx015582s
(2002)Doi:10.1016/0031-9422(81)85279-X
(1981)Doi:10.1016/S0040-4020(01)93277-6
(1981)Doi:10.1039/DT9820000051
(1982)Doi:10.1007/BF00948252
(1982)Doi:10.1039/b100488n
(2001)
