Journal of the Chemical Society. Perkin transactions I p. 3034 - 3040 (1981)
Update date:2022-09-26
Topics:
Maslinska-Solich, Jolanta
Rudnicka, Irena
Jedlinski, Zbigniew J.
The reaction of chiral aluminium alkoxides (2) <(-)-menthyloxide (2a); (-)-2-methylbutoxide (2b); (-)-2-butoxide (2c); and (-)-2-bornanyl oxide (2d)> with (RS)-2-phenylpropanal (1) gives the optically active (S)-(-)-2-phenylpropyl (R)-(-)-2-phenylpropanoate (3), and the mixed esters (-)-menthyl 2-phenylpropanoate (5a), (+)-2-phenylpropyl 2-methylbutanoate (4b), and (+)-2-methylbutyl 2-phenylpropanoate (5b), respectively.An asymmetric disproportionation reaction mechanism has been proposed for compound (1).
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Doi:10.1021/tx015582s
(2002)Doi:10.1016/0031-9422(81)85279-X
(1981)Doi:10.1016/S0040-4020(01)93277-6
(1981)Doi:10.1039/DT9820000051
(1982)Doi:10.1007/BF00948252
(1982)Doi:10.1039/b100488n
(2001)
