Tetrahedron Letters p. 4495 - 4498 (1981)
Update date:2022-09-26
Topics:
Kurosawa, Hideo
Okada, Hiroshi
Hattori, Tatsuaki
Reduction of alkylmercury(II) acetates with N-benzyl-1,4-dihydronicotinamide (BNAH) proceeds through electron-transfer chain-substitution mechanism.The rate constant of hydrogen transfer from BNAH to alkyl radical was estimated as in the order of 105 l/mol.sec.
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