INFLUENCE OF A FREE RADICAL SUBSTITUENT ON REACTIVITY (REVERSE EFFECT). RESULTS INVOLVING BENZYLIC SYSTEMS

DOI: 10.1016/S0040-4039(00)85576-8

Source and publish data:

Tetrahedron Letters p. 5075 - 5078 (1982)

Update date:2022-08-04

Topics:

Authors:

Ballester, M.

Veciana, J.

Riera, J.

Castaner, J.

Rovira, C.

Armet, O.

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Article abstract of DOI:10.1016/S0040-4039(00)85576-8

The first examples of the influence of the free radical character on the reactivity of a non-radical substituent in the radical molecule (reverse effect) are reported.They include thermolysis, reductive dimerization and bromination, involving radicals rel

Full text of DOI:10.1016/S0040-4039(00)85576-8

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