Synthese et reactivite de quelques α-amino azocomposes: mecanisme de la cyclisation thermique en triazoles-1,2,4

DOI: 10.1139/v82-043

Source and publish data:

Canadian Journal of Chemistry p. 285 - 290 (1982)

Update date:2022-08-04

Topics:

Authors:

Metra, Pierre

Hamelin, Jack

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Article abstract of DOI:10.1139/v82-043

The reaction of O-mesitylenesulfonylhydroxylamine (MSH) with hydrazones leads to carbon amination with the formation of α-amino azo compounds.Thermolysis of these compounds affords 1,2,4-triazoles.The mechanism of this cyclization is discussed.

Full text of DOI:10.1139/v82-043

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