Synthesis of Phosphorins by Reaction of 1,2,5-Triphenylphosphole with Alkynes

DOI: 10.1021/jo00133a028

Source and publish data:

Journal of Organic Chemistry p. 2376 - 2379 (1982)

Update date:2022-08-03

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Authors:

Charrier, Claude

Bonnard, Hubert

Mathey, Francois

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Article abstract of DOI:10.1021/jo00133a028

When heated several days at 230 deg C, 1,2,5-triphenylphosphole yields 2,2',3,3',5,5'-hexaphenyl-1,1'-biphospholyl through a transient 2H-phosphole.The reactions of this biphospholyl with lithium, manganese carbonyl, and molybdenum carbonyl are described.

Full text of DOI:10.1021/jo00133a028

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