Engineering of Chiral Crystals for Asymmetric (2? + 2?) Photopolymerization. Execution of an "Absolute" Asymmetric Synthesis with Quantitative Enantiomeric Yield

DOI: 10.1021/ja00376a029

Source and publish data:

Journal of the American Chemical Society p. 3422 - 3429 (1982)

Update date:2022-08-04

Topics:

Authors:

Addadi, Lia

Mil, Jan van

Lahav, Meir

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00376a029

An "absolute asymmetric synthesis" with quantitative enantiomeric yield, via the process of crystallization of a nonchiral compound in a chiral crystal followed by a topochemical photoreaction, has been successfully executed.The needed crystalline chiral

Full text of DOI:10.1021/ja00376a029

Products guided by the article

Product name:(1R,2R,3R,4R)-1-Cyano-2-[4-((E)-2-cyano-2-ethoxycarbonyl-vinyl)-phenyl]-4-{4-[(E)-2-(1-ethyl-propoxycarbonyl)-vinyl]-phenyl}-cyclobutane-1,3-dicarboxylic acid 1-ethyl ester 3-(1-ethyl-propyl) ester

Cas No:81445-50-3

R&D Labs maybe for 81445-50-3

TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town
Qingdao Pana-Life Biochem Co.,Ltd.

Contact:86-532-87683902

Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China

Relevant to this article

Oxidative Cycloamination of Olefins with Aziridines as a Versatile Route to Saturated Nitrogen-Containing Heterocycles

Doi:10.1021/ja037726q
(2003)
Thermal Decomposition of N-Methylpyrrole: Experimental and Modeling Study

Doi:10.1021/j100119a031
(1993)
Spasmolytic agents. I. Aminoalcohol esters having a phenethylamine-like moiety

Doi:10.1248/cpb.30.180
(1982)
Doi:10.1021/ja00375a051
(1982)
(γ-Alkoxyallyl)boronates as Useful Reagents for Preparation of Differentially Protected Diol Derivatives

Doi:10.1021/jo00133a059
(1982)
ADAMANTYLPHENOLS. II. SYNTHESIS AND ANTIVIRAL ACTIVITY OF BROMINATED HYDROQUINONES AND QUINONES CONTAINING AN ADAMANTYL SUBSTITUENT

Doi:10.1007/BF00762033
(1982)

Article Doi