Tetrahedron Letters p. 4533 - 4536 (1981)
Update date:2022-09-26
Topics:
Faustini, Franco
Munari, Sergio De
Panzeri, Achille
Villa, Vittoria
Gandolfi, Carmelo A.
In the reaction of α-aminoacids with excess NaNO2 in polyhydrogen fluoride-pyridine, stereospecific substitution (i.e. retention of configuration) is observed with C6H11CH2CHNH2COOH, while a stereospecific rearrangment occurs in the case of phenylalanine.
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