Stereoselective synthesis of 19-hydroxytaxoid using intramolecular pinacol coupling reaction

DOI: 10.1246/cl.2004.1412

Source and publish data:

Chemistry Letters p. 1412 - 1413 (2004)

Update date:2022-09-26

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Authors:

Mukaiyama, Teruaki

Ogawa, Yasuyuki

Kuroda, Kiichi

Matsuo, Jun-Ichi

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Article abstract of DOI:10.1246/cl.2004.1412

The ABC-ring system of 19-hydroxytaxol is stereoselectively constructed by intramolecular pinacol coupling of diketone 12 with low valent titanium species prepared from TiCl₂ and LiAlH₄. After manipulations of hydroxy protecting grou

Full text of DOI:10.1246/cl.2004.1412

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