Reaction of Allylsilanes and Monothioacetals in the Presence of Lewis Acids: Regioselectivity in the Cleavage of the Acetals

DOI: 10.1039/c39820000459

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Journal of the Chemical Society. Chemical communications p. 459 - 460 (1982)

Update date:2022-08-02

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Authors:

Nishiyama, Hisao

Narimatsu, Shinzo

Sakuta, Koji

Itoh, Kenji

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Article abstract of DOI:10.1039/c39820000459

Trimethylallylsilane reacts with monothioacetals in the presence of tin(IV) chloride, titanium tetrachloride, or boron trifluoride-diethyl ether to give the homoallyl ethers and homoallyl sulphides.

Full text of DOI:10.1039/c39820000459

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