The Synthesis of (15R)-Coleon C and (15S)-Coleon C

DOI: 10.1246/bcsj.60.2435

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2435 - 2444 (1987)

Update date:2022-08-03

Topics:

Authors:

Matsumoto, Takashi

Imai, Sachihiko

Yoshinari, Takashi

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Article abstract of DOI:10.1246/bcsj.60.2435

(15R)-11,16-Dihydroxy-12-methoxymethoxy-8,11,13-abietatrien-7-one and its (15S)-epimer prepared from a C-15 epimeric mixture of 12-methoxy-8,11,13-abietatrien-16-ol, were transformed into (15R)-6,11,12,14,16-pentahydroxy-5,8,11,13-abietatetraen-7-one and its (15S)-epimer; these were identical with natural (15R)-coleon C and (15S)-coleon C, respectively.

Full text of DOI:10.1246/bcsj.60.2435

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