SUR UNE TRANSFORMATION INATTENDUE DU β-METHYL β-NITROSTYRENE EN ALDEHYDE SALICYLIQUE

DOI: 10.1016/0040-4020(81)85014-4

Source and publish data:

Tetrahedron p. 4215 - 4218 (1981)

Update date:2022-08-05

Topics: Experimental Transformation

Authors:

Guillaumel, Jean

Demerseman, Pierre

Royer, Rene

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Article abstract of DOI:10.1016/0040-4020(81)85014-4

An unexpected route to o-hydroxybenzaldehyde is described.Thus, β-methyl β-nitrostyrene mixed with acetyl chloride and aluminium chloride at 0 deg C yields up to 45percent salicylaldehyde besides 2-acetoximino 1-chloro 1-phenyl propane and dichloromethyl benzene as minor products.

Full text of DOI:10.1016/0040-4020(81)85014-4

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