SILICON IN ORGANIC SYNTHESIS. 12. trans-1-BENZENESULFONYL-2-(TRIMETHYLSILYL)ETHYLENE, A DIELS-ALDER DIENOPHILE EQUIVALENT OF ACETYLENE AND MONOSUBSTITUTED ACETYLENES

DOI: 10.1016/S0040-4039(01)83002-1

Source and publish data:

Tetrahedron Letters p. 4643 - 4646 (1981)

Update date:2022-08-02

Topics:

Authors:

Paquette, Leo A.

Williams, Richard V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)83002-1

trans-1-Benzenesulfonyl-2-(trimethylsilyl)ethylene and its 1,2-d₂ derivative enter into Diels-Alder cycloaddition to give products which are smoothly eliminated with fluoride ion.Alkylation of the α-sulfonyl carbanion can precede elimination, s

Full text of DOI:10.1016/S0040-4039(01)83002-1

Products guided by the article

Product name:((1R,2S,3R,4S)-3-Benzenesulfonyl-bicyclo[2.2.1]hept-5-en-2-yl)-trimethyl-silane

Cas No:82262-89-3

R&D Labs maybe for 82262-89-3

ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town
taicang liyuan chemical co,.ltd

website:http://www.tcliyuanchem.com/productse.php

Contact:86-512-53539583

Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China

Relevant to this article

An effective and general method for the highly regioselective synthesis of 1-phenylpyrazoles from β-enaminoketoesters, tandem Blaise-acylation adducts

Doi:10.1039/b820324e
(2009)
Water-triggered, counter-anion-controlled, and silver-phosphines complex-catalyzed stereoselective cascade alkynylation/cyclization of terminal alkynes with salicylaldehydes

Doi:10.1021/jo900079u
(2009)
Enantioselectivity of muscarinic antagonists. 2,2-dicyclohexyl-5-[(dimethylamino)methyl]-1,3-oxathiolane methiodides and related 3-oxides

Doi:10.1021/jm00117a006
(1988)
Doi:10.1021/ja01508a041
(1960)
SYNTHESIS AND PROPERTIES OF sym-TRIAZINE DERIVATIVES. 6. SYNTHESIS OF 2-AMINO- AND 2,4-DIAMINO-sym-TRIAZINES CONTAINING STERICALLY HINDERED PHENOL SEGMENTS

Doi:10.1007/BF00476544
(1987)
1,3-OXYGEN TO OXYGEN REARRANGEMENTS OF GROUP IV ESTERS

Doi:10.1016/S0040-4039(00)95554-0
(1987)

Article Doi