SILICON IN ORGANIC SYNTHESIS. 12. trans-1-BENZENESULFONYL-2-(TRIMETHYLSILYL)ETHYLENE, A DIELS-ALDER DIENOPHILE EQUIVALENT OF ACETYLENE AND MONOSUBSTITUTED ACETYLENES

DOI: 10.1016/S0040-4039(01)83002-1

Source and publish data:

Tetrahedron Letters p. 4643 - 4646 (1981)

Update date:2022-08-02

Topics:

Authors:

Paquette, Leo A.

Williams, Richard V.

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Article abstract of DOI:10.1016/S0040-4039(01)83002-1

trans-1-Benzenesulfonyl-2-(trimethylsilyl)ethylene and its 1,2-d₂ derivative enter into Diels-Alder cycloaddition to give products which are smoothly eliminated with fluoride ion.Alkylation of the α-sulfonyl carbanion can precede elimination, s

Full text of DOI:10.1016/S0040-4039(01)83002-1

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