Alkoxide-Accelerated Sigmatropic Rearrangements. A Novel Entry to the Bicycloundec-7-ene System of the Taxane Diterpenes

DOI: 10.1021/jo00137a039

Source and publish data:

Journal of Organic Chemistry p. 3190 - 3192 (1982)

Update date:2022-08-05

Topics:

Authors:

Martin, Stephen F.

White, James B.

Wagner, Rolf

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00137a039

An anionic oxy-Cope rearrangement serves as the key step in a novel route to the bicyclo<5.3.1>undec-7-ene ring system, which is an important structural element of the taxane diterpenes.

Full text of DOI:10.1021/jo00137a039

Products guided by the article

Product name:2-endo-(1-cyclohexen-1-yl)-6-methylenebicyclo<2.2.2>octan-2-ol

Cas No:82281-10-5

R&D Labs maybe for 82281-10-5

NEW LUNA PHARM CO.,LTD

Contact:Type:+86-0311-85637430

Address:#23.NANSAN ROAD,FENGTAI AREA,BEIJING CITY.
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Shandong LND Bio-tech Co.,Ltd

Contact:15315255144

Address:shandong
Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd

Contact:+86-0372-3662335 +86-0372-3661988

Address:hanling industrial park anyang
Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo

Relevant to this article

Development of CXCR3 antagonists. Part 4: Discovery of 2-amino-(4-tropinyl)quinolines

Doi:10.1016/j.bmcl.2007.11.075
(2008)
Synthesis and Rearrangement of Pyrrolyl Sulfides and Sulfones

Doi:10.1021/jo00140a016
(1982)
Synthesis of radiolabeled juvenile hormone analogs and chiral homologs

Doi:10.1002/bscb.19860950913
(1986)
Doi:10.1016/S0020-1693(00)90352-9
(1982)
On the dehydrogenation of glaucine

Doi:10.1002/ardp.19823150604
(1982)
GIAO/DFT ¹³C NMR Chemical Shifts of 1,3,4-thiadiazoles

Doi:10.1080/10426500701407755
(2007)

Article Doi