Alkoxide-Accelerated Sigmatropic Rearrangements. A Novel Entry to the Bicycloundec-7-ene System of the Taxane Diterpenes

DOI: 10.1021/jo00137a039

Source and publish data:

Journal of Organic Chemistry p. 3190 - 3192 (1982)

Update date:2022-08-05

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Authors:

Martin, Stephen F.

White, James B.

Wagner, Rolf

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Article abstract of DOI:10.1021/jo00137a039

An anionic oxy-Cope rearrangement serves as the key step in a novel route to the bicyclo<5.3.1>undec-7-ene ring system, which is an important structural element of the taxane diterpenes.

Full text of DOI:10.1021/jo00137a039

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