Synthesis of enantiopure cis- and trans-2-aminocyclohexane-1-carboxylic acids from octahydroquinazolin-4-ones

DOI: 10.1016/j.tetasy.2004.08.032

Source and publish data:

Tetrahedron Asymmetry p. 3545 - 3549 (2004)

Update date:2022-09-26

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Authors:

Priego, Jaime

Flores, Patricia

Ortiz-Nava, Claudia

Escalante, Jaime

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Article abstract of DOI:10.1016/j.tetasy.2004.08.032

The chemoselective and diastereoselective hydrogenation of 2,3-dihydro-3-[(S)-α-methylbenzyl]-4-quinazolinone 2 affords octahydroquinazolinones cis-3 and cis-4. Epimerization of cis-3 and cis-4 using t-BuO^-K⁺ produces trans-5 and tra

Full text of DOI:10.1016/j.tetasy.2004.08.032

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Product name:(4aR,8aS)-3-[(S)-α-methylbenzyl]-1,2,4a,5,6,7,8,8a-octahydroquinazolin-4-one

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